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- Chemical Name: VALENCENE
- CAS No.: 4630-07-3
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1.What is the VALENCENE ?
clear colorless to yellowish liquid
ChEBI: A carbobicyclic compound and sesquiterpene that is 1,2,3,4,4a,5,6,7-octahydronaphthalene which is substituted a prop-1-en-2-yl group at position 3 and by methyl groups at positions 4a and 5 (the 3R,4aS,5R diastereoisomer).
(+)-Valencene is a sesquiterpene that has been found in C. sativa and is an aromatic component of orange essence oil. (+)-Valencene (50 μM) induces heme oxgenase-1 (HO-1) expression in macrophages and inhibits the expression of inducible nitric oxide synthase (iNOS), the production of nitric oxide (NO), and the release of high-mobility group box-1 (HMGB1) in RAW 264.7 cells stimulated with LPS. It also increases the survival rate in a mouse model of sepsis induced by cecal ligation and puncture. (+)-Valencene has been used in the synthesis of nootkatone .
2.What is the CAS number for VALENCENE ?
The CAS number of VALENCENE is 4630-07-3.
3.What are another words for VALENCENE ?
Synonyms?for?VALENCENE 4630-07-3:4bH,5a-Eremophila-1(10),11-diene (8CI); Naphthalene,1,2,3,5,6,7,8,8a-octahydro-1,8a-dimethyl-7-(1-methylethenyl)-, [1R-(1a,7b,8aa)]-; Valencene (7CI); (+)-Valencene; 4bH,5a-Eremophila-1(10),11-diene; NSC 148969; Valencen
4.What is VALENCENE (4630-07-3) used for?
(+)-Valencene can be used as a precursor to prepare: (+)-Nootkatone (a sesquiterpene) by dark singlet oxygenation. Benzoyloxyvalencene by reacting with tert-butyl peroxy benzoate via Kharasch?Sosnovsky allylic oxidation method. (+)-Lineariifolianone, a natural product.
InChI:InChI=1/C15H24/c1-11(2)13-8-9-14-7-5-6-12(3)15(14,4)10-13/h7,12-13H,1,5-6,8-10H2,2-4H3
Relevant articles related to VALENCENE:
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Late-Stage Intermolecular Allylic C-H Amination |
Clark, Joseph R.,Dixon, Charlie F.,Feng, Kaibo,Han, Wei,Ide, Takafumi,Koch, Vanessa,Teng, Dawei,Wendell, Chloe I.,White, M. Christina supporting information, p. 14969 - 14975 (2021/10/01) |
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Mechanism-Based Post-Translational Modification and Inactivation in Terpene Synthases |
Kersten, Roland D.,Diedrich, Jolene K.,Yates, John R.,Noel, Joseph P. , p. 2501 - 2511 (2015/12/01) |
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Biotransformation of aristolane- and 2,3-secoaromadendrane-type sesquiterpenoids having a 1,1-dimethylcyclopropane ring by Chlorella fusca var. vacuolata, Mucor species, and Aspergillus niger |
Furusawa, Mai,Hashimoto, Toshihiro,Noma, Yoshiaki,Asakawa, Yoshinori , p. 861 - 868 (2007/10/03) |
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